A covalent triazine framework-based heterogenized Al-Co bimetalliccatalyst for the ring-expansion carbonylation of epoxide to beta-lactone

Collection with item attached
2017
Item details URL
http://open-repository.kisti.re.kr/cube/handle/open_repository/473542.do
DOI
10.1039/c6ra26828e
Title
A covalent triazine framework-based heterogenized Al-Co bimetalliccatalyst for the ring-expansion carbonylation of epoxide to beta-lactone
Description
We acknowledged financial support by the C1 Gas Refinery Program throughthe National Research Foundation of Korea (NRF) funded by the Ministryof Science, ICT & Future Planning (2015M3D3A1A01064879).
abstract
Difficulties in product separation and ineffective recycling of the homogenous catalyst deter the mass production of beta-lactones via carbonylation of epoxides. Herein, we address these issues, for the first time, using a recyclable heterogenized catalyst [bpy-CTF-Al(OTf)(2)][Co(CO)(4)] that efficiently converts propylene oxide (PO) to beta-butyrolactone with high selectivity.
provenance
Made available in Cube on 2018-09-28T10:22:26Z (GMT). No. of bitstreams: 0
language
English
author
Rajendiran, Senkuttuvan
Natarajan, Prakash
Yoon, Sungho
accessioned
2018-09-28T10:22:26Z
available
2018-09-28T10:22:26Z
issued
2017
citation
RSC ADVANCES(7): 8
issn
2046-2069
uri
http://open-repository.kisti.re.kr/cube/handle/open_repository/473542.do
Funder
과학기술정보통신부
Funding Program
기후변화대응기술개발
Project ID
1711048835
Jurisdiction
Rep.of Korea
Project Name
DFT-based design and development of catalysts for carbonylation
rights
openAccess
type
article


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